本文报道了一种边缘定位不对称CoN2O2单原子催化剂,通过跨尺度电极设计将气扩散电极(GDE)活性区域扩展至浸润区,解决了空气自呼吸阴极O2传质受限和易浸润的难题。该策略实现了738.5 mg L-1的H2O2产率(25 mA cm-2,6小时),为无曝气H2O2电合成提供了新范式。
研究人员开发了聚多巴胺修饰卤氧化铋(BiOX)催化剂,通过界面p轨道耦合增强O2吸附并降低·O2?转化能垒,实现3083 μmol g?1 h?1的高效压电催化H2O2生产,为机械能转化提供新策略。
The Nature Index 2025 Research Leaders — previously known as Annual Tables — reveal the leading institutions and countries/territories in the natural and health sciences, according to their output in ...
The Nature Index 2025 Research Leaders — previously known as Annual Tables — reveal the leading institutions and countries/territories in the natural and health sciences, according to their output in ...
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Normal aerobic metabolism (via processes such as photosynthetic and respiratory electron transport chains) in plants yields varied reactive oxygen species (ROS) such as singlet oxygen (1O2), ...
H2O2通过人工光合作用将H2O和O2转化为H2O2被认为是一个环境友善的策略来取代传统的H2O2生产途径。该过程原则上涉及两个半反应: O2的双电子还原(O2+2H++2e−→H2O2,0.68 VRHE)和H2O的氧化(2H2O→H2O2+2H++2e−,1.78 VRHE)。目前,许多光催化剂已被开发耦合氧气还原和水氧化 ...
环氧丙烷(PO)是生产聚氨酯、聚酯、丙二醇等工业化学品的重要中间体。目前,生产PO的主要方法是氯醇法和共氧化法,这两种方法的加工过程都很复杂,而且容易产生多种有害副产品。以钛硅分子筛(TS-1)为催化剂,H2O2为氧化剂,甲醇(CH3OH)为溶剂的H2O2氧化生产PO ...
Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka565-0871, Japan Innovative Catalysis Science Division, Institute for Open ...
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